Influences of Potential and pH on Initiation of Environment-Assisted Cracking of Ti-6Al-4V

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We have investigated the influences of potential and pH on environment-assisted cracking (EAC) of Ti–6Al–4V in aqueous solutions. The EAC test was conducted by slow strain rate technique. Solution pH was controlled from 1 to 7, and applied potential was fixed between −1.8 and +0.2 V<SUB>SHE</SUB>. In the solutions of pHs 3 and 7, mechanical properties of the material was almost independent of applied potential. This means that the material shows almost no EAC susceptibility in the potential-pH region for the EAC test period. At pH 1, however, both maximum stress and fracture strain changed with applied potential, and showed minimum values at an applied potential of about −1.0 V<SUB>SHE</SUB>. According to surface analyses by scanning electron microscopy and X-ray diffraction technique, some cracks and Ti hydride were detected from only the specimens fractured at about −1.0 V<SUB>SHE</SUB> in the solution of pH 1. Therefore, it can be concluded that Ti–6Al–4V is most susceptible to the EAC at about −1.0 V<SUB>SHE</SUB> and a pH less than 1. The EAC region was in good agreement with Ti ion stable region in a potential-pH diagram of Ti/water system, and was quite similar to that on the EAC of TiAl.

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  • Materials transactions  

    Materials transactions 46(10), 2190-2196, 2005-10-01 

    The Japan Institute of Metals and Materials

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各種コード

  • NII論文ID(NAID)
    10018277607
  • NII書誌ID(NCID)
    AA1151294X
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    13459678
  • NDL 記事登録ID
    7487810
  • NDL 雑誌分類
    ZP41(科学技術--金属工学・鉱山工学)
  • NDL 請求記号
    Z53-J286
  • データ提供元
    CJP書誌  CJP引用  NDL  J-STAGE 
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