ポリエチレングリコールのDIOSマススペクトルにおけるカチオン化剤の影響 Effects of Cationizing Agents on DIOS Mass Spectra of Poly(ethylene glycol)s

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Desorption/ionization on silicon (DIOS)-mass spectrometry of poly(ethylene glycol)s (PEG) were investigated using binary mixtures of NaI and other alkali metal iodides (LiI, KI, RbI, and CsI). A linear correlation was found between the relative ion intensities and the concentration ratios of the alkali metal ions. The smaller size metal ion adducts of PEG molecules were observed more intensively in the spectra. These results suggest that the interaction between PEG molecules and cationizing agents is important for the cationization of PEG molecules in DIOS.

Desorption/ionization on silicon (DIOS)-mass spectrometry of poly(ethylene glycol)s (PEG) were investigated using binary mixtures of NaI and other alkali metal iodides (LiI, KI, RbI, and CsI). A linear correlation was found between the relative ion intensities and the concentration ratios of the alkali metal ions. The smaller size metal ion adducts of PEG molecules were observed more intensively in the spectra. These results suggest that the interaction between PEG molecules and cationizing agents is important for the cationization of PEG molecules in DIOS.

収録刊行物

  • 質量分析 = Mass spectroscopy  

    質量分析 = Mass spectroscopy 53(5), 265-269, 2005-10-01 

    The Mass Spectrometry Society of Japan

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各種コード

  • NII論文ID(NAID)
    10018281446
  • NII書誌ID(NCID)
    AN0010555X
  • 本文言語コード
    JPN
  • 資料種別
    ART
  • ISSN
    13408097
  • NDL 記事登録ID
    7713647
  • NDL 雑誌分類
    ZP4(科学技術--化学・化学工業--分析化学)
  • NDL 請求記号
    Z17-213
  • データ提供元
    CJP書誌  NDL  IR  J-STAGE 
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