アニオン重合の基礎から最近の進歩 : 4. リビングアニオン重合による特殊形態高分子の精密合成 Fundamental Studies and Recent Advances in Anionic Polymerization : 4. Precise Synthesis of Macromolecules with Designed Architectures by Means of Living Anionic Polymerization

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著者

    • 杉山 賢次 SUGIYAMA Kenji
    • 南京工業大学大学院理工学研究科有機・高分子物質専攻 Polymeric and Organic Materials Department, Graduate School of Science and Engineering, Tokyo Institute of Technology
    • 平尾 明 HIRAO Akira
    • 南京工業大学大学院理工学研究科有機・高分子物質専攻 Polymeric and Organic Materials Department, Graduate School of Science and Engineering, Tokyo Institute of Technology

抄録

Recent advances in precise synthesis of macromolecules with specially designed architectures will be reviewed in this paper. Such designed macromolecules include graft copolymers, comb-like polymers, cyclic polymers, regular and asymmetric star-branched polymers, and a variety of hyperbranched polymers with complexed structures as well as block copolymers and chain-end-functionalized polymers synthesized by living (anionic) polymerization. Their architectures are well defined in branching, position, and shape and chain structures are precisely controlled in molecular weights and molecular weight distributions. Recently, new macromolecules with more complex branched architectures have been further synthesized along with rapid progress of living anionic polymerization and new development of living polymerization systems with different mechanisms. These are star-branched polymers with many arms and multi-components, highly dense comb-like polymers having one polymer segment in each unit, star-linear block polymers, comb-like graft and star polymers, dendritic hyperbranched polymers. A particular example is a seventhgeneration well-defined dendrimer-like star-branched polymer having a <i>M</i><sub>n</sub> of 2000000 and comprised of 508 polymer segments and 512 end-functionalities. They are characteristic and quite different from linear polymers in physical property and behavior in solution, melt, and solid state. Furthermore, their different segments are segregated and self-organized at molecular level to form novel nano-scale supra-structures and molecular assemblies.

収録刊行物

  • 日本ゴム協會誌

    日本ゴム協會誌 80(3), 100-106, 2007-03-15

    THE SOCIRETY OF RUBBER SCIENCE AND TECHNOLOGYY, JAPAN

参考文献:  41件中 1-41件 を表示

  • <no title>

    MORTON M.

    Anionic Polymerization : Principles and Practice, 1983

    被引用文献1件

  • <no title>

    MOLAU G. E.

    Block Polymers, 1970

    被引用文献1件

  • <no title>

    MISHRA M. K. Eds.

    Star and Hyperbranched Polymers, 1999

    被引用文献1件

  • <no title>

    SEMLYEN J. A. Ed.

    Cyclic Polymers, 1986

    被引用文献1件

  • <no title>

    HUKSTADT H.

    Macromol. Chem. Phys. 201, 1741, 2000

    被引用文献1件

  • <no title>

    HSIEH H. L.

    Anionic Polymerization ; Principles and Practical Applications, 1996

    被引用文献1件

  • <no title>

    HSIEH H. L.

    Anionic Polymerization ; Principles and Practical Applications, 1996

    被引用文献1件

  • <no title>

    HOEBEN F. J. M.

    Chem. Rev. 105, 1491, 2005

    被引用文献1件

  • <no title>

    HIRAO A.

    Polymer J. 34, 633, 2002

    被引用文献1件

  • <no title>

    HSIEH H. L.

    Anionic Polymerization ; Principles and Practical Applications, 1996

    被引用文献1件

  • <no title>

    LUTZ P. J.

    Star and Hyperbranched Polymers, 1999

    被引用文献1件

  • <no title>

    HADJICHRISTIDIS N.

    Adv. Polym. Sci. 142, 72, 1999

    被引用文献1件

  • <no title>

    HIGASHIHARA T.

    Macromolecules 38, 4577, 2005

    被引用文献1件

  • <no title>

    HIRAO A.

    Macromolecules 39, 6081, 2006

    被引用文献1件

  • <no title>

    HIRAO A.

    J. Polym. Sci., Part A, Polym. Chem. 44, 6659, 2006

    被引用文献1件

  • <no title>

    MATSUO A.

    Macromolecules 37, 6283, 2004

    被引用文献1件

  • <no title>

    HIRAO A.

    Macromolecules 38, 8701, 2005

    被引用文献1件

  • 光学活性モノヒドロキシ脂肪酸の合成

    飛田 憲一 , 滝川 浩郷 , 三宅 秀芳 , 佐々木 満

    講演要旨集 30, 111, 2005-03-10

    被引用文献6件

  • Metal-catalyzed living radical polymerization

    KAMIGAITO M.

    Chemi Rev 101, 3689-3745, 2001

    被引用文献52件

  • Atom transfer radical polymerization

    MATYJASZEWSKY K.

    Chem. Rev. 101, 2921-2990, 2001

    被引用文献76件

  • <no title>

    SUGIYAMA K.

    Macromol. Chem. Phys. 197, 3149, 1996

    被引用文献4件

  • <no title>

    LOYKULNANT S.

    Macromolecules 24, 8434, 2001

    DOI 被引用文献1件

  • <no title>

    EL-SHEHAWY A. A.

    Macromolecules 38, 8285, 2005

    DOI 被引用文献4件

  • <no title>

    HADJICHRISTIDIS N.

    Chem. Rev. 101, 3747, 2001

    被引用文献13件

  • <no title>

    PARASKEVA S.

    J. Polym. Sci., Part A : Polymer Chem. 38, 931, 2000

    被引用文献1件

  • <no title>

    TSUKAHARA Y.

    Polym. J. 26, 1013, 1994

    被引用文献5件

  • <no title>

    SCHAPPACHER M.

    Macromol. Chem. Phys. 198, 3953, 1997

    被引用文献2件

  • <no title>

    SCHAPPACHER M.

    Macromolecules 33, 7371, 2000

    被引用文献1件

  • <no title>

    RYU S. W.

    Macromolecules 33, 4765, 2000

    被引用文献1件

  • <no title>

    RYU S. W.

    Macromolecules 35, 7191, 2002

    被引用文献1件

  • <no title>

    BAUER B. J.

    Rubber Chem. Technol. 51, 406, 1978

    被引用文献3件

  • <no title>

    HADJICHRISTIDIS N.

    J. Polym. Sci., Part A : Polym. Chem. 37, 857, 1999

    被引用文献3件

  • <no title>

    HIRAO A.

    Macromolecules 35, 7224, 2002

    被引用文献3件

  • <no title>

    HIRAO A.

    Macromolecules 36, 9742, 2003

    被引用文献2件

  • <no title>

    HIRAO A.

    Macromol. Chem. Phys. 202, 3165, 2001

    被引用文献2件

  • <no title>

    HIRAO A.

    Macromolecules 35, 7238, 2002

    被引用文献2件

  • <no title>

    ZHAO Y.

    J. Am. Chem. Soc. 127, 14158, 2005

    DOI 被引用文献1件

  • <no title>

    TROLLSAS M.

    J. Am. Chem. Soc. 120, 4644, 1998

    DOI 被引用文献7件

  • <no title>

    ANGOT S.

    Macromolecules 33, 5418, 2000

    被引用文献5件

  • <no title>

    PERCEC V

    J. Am. Chem. Soc. 125, 6503, 2003

    被引用文献4件

各種コード

  • NII論文ID(NAID)
    10018295418
  • NII書誌ID(NCID)
    AN00189720
  • 本文言語コード
    JPN
  • 資料種別
    REV
  • ISSN
    0029022X
  • NDL 記事登録ID
    8743038
  • NDL 雑誌分類
    ZP17(科学技術--化学・化学工業--高分子化学・高分子化学工業--ゴム・プラスチックス)
  • NDL 請求記号
    Z17-125
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    CJP書誌  NDL  J-STAGE 
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