電子移動反応による炭素カチオンの創製を機軸とする新しい有機合成 Organic Synthesis Using Carbocations Generated by Electron Transfer Reactions

この論文にアクセスする

この論文をさがす

著者

    • 菅 誠治 SUGA Seiji
    • 京都大学大学院工学研究科合成・生物化学専攻 Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University

抄録

We have developed the "cation pool" method in which carbocations such as alkoxycarbenium ions and <I>N</I>-acyliminium ions are generated and accumulated in conventional reaction media by low temperature electrochemical oxidation. The carbocations thus produced are allowed to react with a variety of nucleophiles. Various organic transformations using the cation pool method, such as reductive radical couplings, cationic carbohydroxylations, three-component couplings, and additions of organic radicals, have also been developed. Combinatorial sequential synthesis using the "cation flow" method, in which carbocations are generated in an electrochemical microflow system, has been achieved as well.

収録刊行物

  • 有機合成化学協会誌 : JOURNAL OF Synthetic Organic Chemistry JAPAN  

    有機合成化学協会誌 : JOURNAL OF Synthetic Organic Chemistry JAPAN 64(10), 1010-1020, 2006-10-01 

    The Society of Synthetic Organic Chemistry, Japan

参考文献:  66件

参考文献を見るにはログインが必要です。ユーザIDをお持ちでない方は新規登録してください。

各種コード

  • NII論文ID(NAID)
    10018311446
  • NII書誌ID(NCID)
    AN0024521X
  • 本文言語コード
    JPN
  • 資料種別
    ART
  • ISSN
    00379980
  • NDL 記事登録ID
    8536405
  • NDL 雑誌分類
    ZP11(科学技術--化学・化学工業--有機化学・有機化学工業)
  • NDL 請求記号
    Z17-256
  • データ提供元
    CJP書誌  NDL  J-STAGE 
ページトップへ