Terahertz Time-domain Spectra of Inter- and Intramolecular Hydrogen Bonds of Fumaric and Maleic Acids

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<jats:title>Abstract</jats:title> <jats:p>The inter- and intramolecular hydrogen-bonding modes of two steric isomers, namely fumaric acid and maleic acid, are observed by using terahertz time-domain spectroscopy (THz-TDS). The intermolecular modes observed with fumaric acid crystals are inactivated by incorporating the molecules in the nano-sized pores of a mesoporous silicate (SBA-16) due to the separation of the molecules, whereas the intramolecular modes of maleic acid of the crystal and the incorporated samples are similar.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 35 (10), 1128-1129, 2006-09-09

    Oxford University Press (OUP)

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