Oxidation of 1,3-Diphosphacyclobutane-2,4-diyl with Ammoniumyl Antimonate and EPR Study of the Corresponding Cation Radical

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抄録

A sterically protected biradical species, 1-<I>tert-</I>butyl-3-methyl-2,4-bis(2,4,6-tri-<I>tert</I>-butylphenyl)-1,3-diphosphacyclobutane-2,4-diyl was allowed to react with tris(4-bromophenyl)ammoniumyl hexachloroantimonate as an oxidant and the product was analyzed by EPR to show that the biradical was oxidized to give the corresponding radical cation species. The structure of the cation radical was also supported by ab initio calculations on a model compound.

収録刊行物

  • Chemistry letters  

    Chemistry letters 35(10), 1136-1137, 2006-10-05 

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10018323103
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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