Fluorescent Molecular Sensing for Various Types of Surfactants Using Amino-β-cyclodextrins Bearing Naphthalene Chromophore

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著者

    • NAKASHIMA Hironori
    • Group of Molecular Materials Chemistry, Section of Environmental Materials Science, Faculty of Environmental Earth Science, Hokkaido University
    • YOSHIDA Noboru
    • Group of Molecular Materials Chemistry, Section of Environmental Materials Science, Faculty of Environmental Earth Science, Hokkaido University

抄録

Fluorescent spectroscopic studies on the complexation of naphthalene-appended amino-β-cyclodextrins, <B>1</B> and <B>2</B>, with anionic, cationic, and nonionic surfactants have been carried out. In host <B>1</B>–surfactant system, an excellent fluorescent signal change was observed. On the other hand, host <B>2</B> exhibits no photophysical response in the presence of various surfactants. The difference in the properties between <B>1</B> and <B>2</B> was interpreted by difference in the inclusion depth of the naphthalene units for the cyclodextrin cavity. The binding abilities and thermodynamic (Δ<I>H</I>°, Δ<I>S</I>°, and Δ<I>G</I>°) quantities of <B>1</B>–surfactant system have been discussed to characterize structure/enegetics for the complexation process.

収録刊行物

  • Chemistry letters

    Chemistry letters 35(10), 1168-1169, 2006-10-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10018323422
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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