Grafting Organic and Biomolecules on H-Terminated Porous Silicon from a Diazirine

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  • Shuai Wei
    State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University
  • Jing Wang
    State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University
  • Dong-Jie Guo
    State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University
  • Ya-Qing Chen
    State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University
  • Shou-Jun Xiao
    State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University

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<jats:title>Abstract</jats:title> <jats:p>A diazirine compound, 1,4-(1-azi-2,2,2-trifluoroethyl)benzoic acid, was used as a stable carbene precursor to react with Si–H terminated porous silicon (PSi) under microwave irradiation. After formation of a molecular monolayer, the end carboxyl group was converted to an amine-reactive crosslinker species, NHS ester, and finally to a Bovine Serum Albumin (BSA) monolayer on PSi.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 35 (10), 1172-1173, 2006-09-16

    Oxford University Press (OUP)

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