Immobilization of a Binuclear Ruthenium(III) Complex on a Gold (111) Surface : Observations of Proton-coupled Electron Transfer and Electrochemical Durability in Aqueous Media

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著者

    • ABE Masaaki
    • Department of Applied Chemistry, Graduate School of Engineering, Kyushu University
    • HISAEDA Yoshio
    • Department of Applied Chemistry, Graduate School of Engineering, Kyushu University
    • UOSAKI Kohei
    • Division of Chemistry, Graduate School of Science, Hokkaido University
    • SASAKI Yoichi
    • Division of Chemistry, Graduate School of Science, Hokkaido University

抄録

An oxo-bridged diruthenium(III) complex was immobilized on a Au(111) electrode through the coordination by terminal pyridyl groups of self-assembled monolayer of alkyl chains, and the immobilized complex underwent proton-coupled electron-transfer reactions in a very wide pH range (2–12) with remarkable monolayer durability for multiple potential cycles.

収録刊行物

  • Chemistry letters

    Chemistry letters 35(10), 1178-1179, 2006-10-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10018323533
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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