Application of Association Model for Solubilities of Alkali Metal Chloride in Water Vapor at High Temperatures and Pressures

  • Higashi Hidenori
    Division of Material Engineering, Graduate School of Natural Science and Technology, Kanazawa University
  • Iwai Yoshio
    Department of Chemical Engineering, Faculty of Engineering, Kyushu University
  • Kitani Yoshiaki
    Department of Chemical Engineering, Faculty of Engineering, Kyushu University
  • Matsumoto Kota
    Department of Chemical Engineering, Faculty of Engineering, Kyushu University
  • Shimoyama Yusuke
    Department of Chemical Engineering, Faculty of Engineering, Kyushu University
  • Arai Yasuhiko
    Department of Chemical Engineering, Faculty of Engineering, Kyushu University

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An association model with a cubic equation of state was adopted to calculate the solubilities of alkali metal chlorides in water vapor under high temperatures and pressures. The solubilities of sodium chloride (NaCl) and potassium chloride (KCl) were correlated by optimized association numbers and equilibrium constants. The correlated results represented well the experimental results. The logarithm of equilibrium constants show linear functions of reciprocal of the absolute temperature.

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