Evolved Gas Analysis Using Photoionization Mass Spectrometry

• ARII Tadashi

  Strategic Business Unit Thermal Analysis Group, Rigaku Corporation

• OTAKE Satoshi

  Strategic Business Unit Thermal Analysis Group, Rigaku Corporation

• TAKATA Yoshihiro

  Strategic Business Unit Thermal Analysis Group, Rigaku Corporation

• MATSUURA Shigeki

  Electron Tube Division, HAMAMATSU PHOTONICS K.K.

抄録

Photoionization (PI) with vacuum ultraviolet (VUV) light provides an efficient and fragmentation-free method for the soft ionization of gaseous compounds. A photoionization source with a deuterium (D₂) lamp for PI was installed in a vacuum chamber in the ionization chamber of a mass spectrometer. The PI mass spectrometry (PIMS) was applied to the evolved gas analysis (EGA) system for the volatilization of organic solvents and thermal decomposition of polymers in an inert gas atmosphere. The PI mass spectrum obtained was satisfactorily characterized by only the parent ions with no contribution as a result of fragmentation during ionization. The results suggested that EGA-PIMS was an especially powerful and desirable in situ thermal analysis method for substances which evolve organic gases simultaneously and sequentially. The combination of a VUV-light source with a quadropole-mass spectrometer in EGA is described briefly, and the results compared with EGA using conventional electron impact ionization mass spectrometry are presented.

収録刊行物

• 質量分析

  質量分析 54 (6), 243-249, 2006

  一般社団法人 日本質量分析学会

キーワード

• Photoionization
• EGA-MS
• Fragmentation-free
• Thermal decomposition
• VOC

詳細情報

• CRID: 1390282681471225216
• NII論文ID: 10018403900
• NII書誌ID: AN0010555X
• DOI: 10.5702/massspec.54.243
• ISSN: 18804225
• ISSN: 18843271
• ISSN: 13408097
• NDL書誌ID: 8599740
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I8599740
• Web Site: http://www.jstage.jst.go.jp/article/massspec/54/6/54_6_243/_pdf
• 本文言語コード: en
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可