Giant Spherulite Formation in Amorphous Polyanion Membrane by Photopolymerization on Gelatin Matrix

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著者

    • YAO Bo-long
    • School of Chemical Engineering, Nanjing University of Science and Technology
    • SONG Hong-chang
    • School of Chemical Engineering, Nanjing University of Science and Technology
    • LU Lu-de
    • School of Chemical Engineering, Nanjing University of Science and Technology
    • CHEN Ming-qing
    • School of Chemical and Material Engineering, Southern Yangtze University
    • KANEKO Tatsuo
    • School of Materials Science, Japan Advanced Institute of Science and Technology
    • AKASHI Mitsuru
    • School of Chemical and Material Engineering, Southern Yangtze University

抄録

In-bulk photopolymerization of 2-acylamido-2-methylpropanesulphonic acid (AMPS) on gelatin matrix was made by ultraviolet irradiation at room temperature to form the crystalline and flexible membranes with giant spherulites (maximal radius: 2.2 cm). Number- and weight-average molecular weights of PAMPS were 79,500 and 138,000, respectively. The melting point of the membrane was around 200 °C. The giant spherulite formation was discussed on the basis of the PAMPS chain formation and PAMPS/gelatin complexation.

収録刊行物

  • Chemistry letters

    Chemistry letters 35(11), 1228-1229, 2006-11-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10018404679
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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