Osmium Complex Grafted on a Carbon Electrode Surface as a Mediator for a Bioelectrocatalytic Reaction

この論文にアクセスする

この論文をさがす

著者

    • TSUJIMURA Seiya
    • Division of Applied Life Sciences, Graduate School of Agriculture, Kyoto University
    • KATAYAMA Aya
    • Division of Applied Life Sciences, Graduate School of Agriculture, Kyoto University
    • KANO Kenji
    • Division of Applied Life Sciences, Graduate School of Agriculture, Kyoto University

抄録

A novel electrochemical modification method of carbon electrodes with redox active amines is proposed for mediated electron transfer between enzymes and electrodes. Histamine-coordinated Os complex was synthesized as a model redox amine. The electro-oxidation of the complex generated a stable covalent linkage between the nitrogen atom of the amino group and the carbon atom of the electrode surface. The covalent-linked Os complex on the electrode showed a good redox response and a high activity as an electron-transfer mediator between the electrode and a model enzyme: PQQ-dependant water-soluble glucose dehydrogenase.

収録刊行物

  • Chemistry letters  

    Chemistry letters 35(11), 1244-1245, 2006-11-05 

    The Chemical Society of Japan

参考文献:  9件

参考文献を見るにはログインが必要です。ユーザIDをお持ちでない方は新規登録してください。

各種コード

  • NII論文ID(NAID)
    10018404836
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
ページトップへ