Osmium Complex Grafted on a Carbon Electrode Surface as a Mediator for a Bioelectrocatalytic Reaction
-
- Tsujimura Seiya
- Division of Applied Life Sciences, Graduate School of Agriculture, Kyoto University
-
- Katayama Aya
- Division of Applied Life Sciences, Graduate School of Agriculture, Kyoto University
-
- Kano Kenji
- Division of Applied Life Sciences, Graduate School of Agriculture, Kyoto University
この論文をさがす
抄録
A novel electrochemical modification method of carbon electrodes with redox active amines is proposed for mediated electron transfer between enzymes and electrodes. Histamine-coordinated Os complex was synthesized as a model redox amine. The electro-oxidation of the complex generated a stable covalent linkage between the nitrogen atom of the amino group and the carbon atom of the electrode surface. The covalent-linked Os complex on the electrode showed a good redox response and a high activity as an electron-transfer mediator between the electrode and a model enzyme: PQQ-dependant water-soluble glucose dehydrogenase.
収録刊行物
-
- Chemistry Letters
-
Chemistry Letters 35 (11), 1244-1245, 2006
公益社団法人 日本化学会
- Tweet
キーワード
詳細情報 詳細情報について
-
- CRID
- 1390282679560984576
-
- NII論文ID
- 10018404836
-
- NII書誌ID
- AA00603318
-
- COI
- 1:CAS:528:DC%2BD28Xht1GrtbfI
-
- ISSN
- 13480715
- 03667022
-
- 本文言語コード
- en
-
- データソース種別
-
- JaLC
- Crossref
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用不可