Novel Deconjugative Esterification of 2-Cyclohexylideneacetic Acids through 4-(Pyrrolidin-1-yl)pyridine-catalyzed Carbodiimide Couplings

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著者

    • SANO Shigeki
    • Graduate School of Pharmaceutical Sciences, The University of Tokushima
    • HARADA Etsuko
    • Graduate School of Pharmaceutical Sciences, The University of Tokushima
    • AZETSU Tomohiro
    • Graduate School of Pharmaceutical Sciences, The University of Tokushima
    • ICHIKAWA Takashi
    • Graduate School of Pharmaceutical Sciences, The University of Tokushima
    • NAKAO Michiyasu
    • Graduate School of Pharmaceutical Sciences, The University of Tokushima
    • NAGAO Yoshimitsu
    • Graduate School of Pharmaceutical Sciences, The University of Tokushima

抄録

4-(Pyrrolidin-1-yl)pyridine-catalyzed deconjugative esterification of 2-cyclohexylideneacetic acids afforded isopropyl 2-(cyclohex-1-enyl)acetate by employing 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide hydrochloride as a coupling reagent. On the other hand, 4-(pyrrolidin-1-yl)pyridine-catalyzed esterification with 1,3-dicyclohexylcarbodiimide was not accompanied by deconjugation and gave isopropyl 2-cyclohexylideneacetate.

収録刊行物

  • Chemistry letters

    Chemistry letters 35(11), 1286-1287, 2006-11-05

    公益社団法人 日本化学会

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各種コード

  • NII論文ID(NAID)
    10018405161
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  IR  J-STAGE 
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