Submicro- and Nanocrystals of Cyano-bridged FeLa Coordination Polymer in Reversed Micelle
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Submicro- and nanocrystals of a d–f heteronuclear coordination polymer, La[Fe(CN)<SUB>6</SUB>]·<I>n</I>H<SUB>2</SUB>O, were prepared in the water-in-oil microemulsion using AOT or NP-5 as a surface-protecting agent. When AOT was used, size and shape of the crystals were remarkably influenced by their preparation conditions, whereas little changed when NP-5 was used. These results were explained by the different protecting abilities of anionic AOT and nonionic NP-5.
- Chemistry Letters
Chemistry Letters 35(11), 1302-1303, 2006-11-05
The Chemical Society of Japan