Millimeter-Wave Rotational Spectrum of CF_3CCD in the Ground and Excited Vibrational States υ_<10> = 1

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Millimeter-wave rotational spectra of the symmetric top molecule CF<SUB>3</SUB>CCD have been measured in its ground and excited vibrational states, <I>v</I><SUB>10</SUB> = 1. Analysis of the ground-state spectra gave the following rotational parameters: <I>B</I><SUB>0</SUB> = 2696.06753 MHz, <I>D<SUB>J</SUB></I> = 0.22759 kHz, <I>D<SUB>Jk</SUB></I> = 6.1748 kHz. <I>H<SUB>Jk</SUB></I> (16.1 mHz) and <I>H<SUB>kJ</SUB></I> (−0.243 mHz) were determined for the first time. In the <I>v</I><SUB>10</SUB> = 1 state, <I>l</I> = ±1 series have been assigned and spectroscopic parameters were obtained accurately: <I>B</I><SUB>1</SUB> = 2701.26211 MHz, <I>q<SUB>t</SUB></I><SUP>+</SUP>(2,2) = 3.30887 MHz, <I>A</I>ζ = 3263.93 MHz. The off diagonal parameter <I>r<SUB>t</SUB></I> (0.152 MHz) was determined for the first time.

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  • Bulletin of the Chemical Society of Japan

    Bulletin of the Chemical Society of Japan 79(12), 1876-1880, 2006-12-15

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10018442136
  • NII書誌ID(NCID)
    AA00580132
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    00092673
  • NDL 記事登録ID
    8567393
  • NDL 雑誌分類
    ZP1(科学技術--化学・化学工業)
  • NDL 請求記号
    Z53-B35
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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