Characterization of a Glucose Sensor Prepared by Electropolymerization of Pyrroles Containing a Tris-bipyridine Osmium Complex

• TSUJIMOTO Masaki

  Department of Chemical Science and Technology, Faculty of Engineering, The University of Tokushima

• YABUTANI Tomoki

  Department of Chemical Science and Technology, Faculty of Engineering, The University of Tokushima

• SANO Atsushi

  Department of Chemical Science and Technology, Faculty of Engineering, The University of Tokushima

• TANI Yuji

  Department of Chemical Science and Technology, Faculty of Engineering, The University of Tokushima

• MUROTANI Hiroki

  Department of Chemical Science and Technology, Faculty of Engineering, The University of Tokushima

• MISHIMA Yuji

  Takasago Technical Center, Tsurui Chemical Co. Ltd.

• MARUYAMA Kenichi

  Departments of Applied Chemistry and of Information and Computer Science, Faculty of Science and Technology, Keio University

• YASUZAWA Mikito

  Department of Chemical Science and Technology, Faculty of Engineering, The University of Tokushima

• MOTONAKA Junko

  Department of Chemical Science and Technology, Faculty of Engineering, The University of Tokushima

抄録

A glucose sensor was developed by electrocopolymerization using pyrroles containing a tris-bipyridine (bpy) osmium complex (Os-py), pyrrole (py), pyrrole propanoic acid (PPA) and glucose oxidase (GOx) to improve the key performance characteristics, such as the sensitivity, selectivity, and long-term stability. Tris-bipyridine osmium pyrrole complexes with four different methylene moieties were utilized to correlate the methylene length with the glucose sensor performance. The electrocatalytic response of glucose was clearly observed at electrodes modified with Os-py, except for the electrode immobilized with the Os-py complex containing the shortest methylene moiety. The current response to glucose increased up to a concentration of 100 mmol dm^-3. The electrocatalytic response to glucose at the [Os(bpy)₂(py(6)-bpy)]^2+/3+/py/PPA/GOx electrode was stable for more than 100 days. Dissolved oxygen and potential interference compounds (ascorbic acid, uric acid, and acetaminophen) minimally perturbed the current response to glucose at the [Os(DM-bpy)₂(py(6)-bpy)]^2+/3+/py/PPA/GOx electrode. Based on these results, a longer methylene moiety appears to improve the performance characteristics of a glucose sensor fabricated via the electropolymerization of tris-bipyridine osmium pyrrole complexes.

収録刊行物

• Analytical Sciences

  Analytical Sciences 23 (1), 59-63, 2007

  社団法人 日本分析化学会

キーワード

• Analytical Chemistry

詳細情報

• CRID: 1390001204255361408
• NII論文ID: 130004441370
• NII論文ID: 10018464105
• NII書誌ID: AA10500785
• DOI: 10.2116/analsci.23.59
• COI: 1:STN:280:DC%2BD2s%2Fhs1Kisg%3D%3D
• ISSN: 13482246
• ISSN: 09106340
• NDL書誌ID: 8598140
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I8598140
• Web Site: https://link.springer.com/content/pdf/10.2116/analsci.23.59.pdf
• Web Site: https://link.springer.com/article/10.2116/analsci.23.59/fulltext.html
• Web Site: http://www.jstage.jst.go.jp/article/analsci/23/1/23_1_59/_pdf
• 本文言語コード: en
• データソース種別:
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  • NDL
  • Crossref
  • CiNii Articles
  • KAKEN
• 抄録ライセンスフラグ: 使用不可