錯体重合法による酸化物粉体の精密化学合成と高機能化 Precisely-Controlled Synthesis of Oxide Powders by Polymerizable Complex Method Towards High-Performance

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著者

    • 垣花 眞人 KAKIHANA Masato
    • 東北大学多元物質科学研究所 Institution of Multidisciplinary Research for Advanced Materials, Tohoku University

抄録

The "polymerizable complex (PC)" method has been developed to prepare copper based high-<I>T</I><SUB>c</SUB> superconductors with outstandingly high purity, photocatalysts for water decomposition with high activity and phosphor materials with excellent emission intensities. The PC method is based upon formation of metal complexes and subsequent polyesterification between a hydroxy-caroboxylic acid such as citric acid and a glycol such as propylene glycol, keeping metal species homogeneous on the molecular scale inside the polyester resin precursor. The PC method is also an efficient methodology for testing promising compounds with less tailoring efforts of synthesis for each candidate; a scheme to search for potential phosphors has been demonstrated as a representative example.

収録刊行物

  • 粉体および粉末冶金  

    粉体および粉末冶金 54(1), 32-38, 2007-01-15 

    Japan Society of Powder and Powder Metallurgy

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各種コード

  • NII論文ID(NAID)
    10018499483
  • NII書誌ID(NCID)
    AN00222724
  • 本文言語コード
    JPN
  • 資料種別
    REV
  • ISSN
    05328799
  • NDL 記事登録ID
    8669966
  • NDL 雑誌分類
    ZP41(科学技術--金属工学・鉱山工学)
  • NDL 請求記号
    Z17-274
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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