Pd-catalyzed Coupling Reaction of Allyl and Propargyl Ethers with Chlorosilanes

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著者

    • NAITOH Yoshitaka
    • Department of Applied Chemistry, Graduate School of Engineering, Osaka University
    • BANDO Fumiaki
    • Department of Applied Chemistry, Graduate School of Engineering, Osaka University
    • TERAO Jun
    • Science and Technology Center for Atoms, Molecules and Ions Control, Graduate School of Engineering, Osaka University
    • OTSUKI Kazutaka
    • Department of Applied Chemistry, Graduate School of Engineering, Osaka University
    • KUNIYASU Hitoshi
    • Department of Applied Chemistry, Graduate School of Engineering, Osaka University
    • KAMBE Nobuaki
    • Department of Applied Chemistry, Graduate School of Engineering, Osaka University

抄録

Pd-catalyzed synthesis of allylsilanes from chlorosilanes and allyl ethers is described. The reaction proceeds efficiently at room temperature by the use of phenyl or vinyl Grignard reagent in the presence of palladium catalysts. The present method can also be applied to synthesis of propargylsilanes by the use of propargyl ethers.

収録刊行物

  • Chemistry letters

    Chemistry letters 36(2), 236-237, 2007-02-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10018522351
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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