Size- and Stereo-specific Accommodation of Alkanes and Alkenes in Calixarene-based Microporous Solids

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著者

    • ISHII Yusuke
    • Graduate School of Environmental Science and Creative Research Initiative 'Sosei', Hokkaido University
    • NAKAYAMA Naoki
    • Graduate School of Environmental Science and Creative Research Initiative 'Sosei', Hokkaido University
    • KONISHI Katsuaki
    • Graduate School of Environmental Science and Creative Research Initiative 'Sosei', Hokkaido University

抄録

Hydrophobic micropores created in the crystal lattice of a calix[4]arene–polyoxometalate hybrid (C2-PW) selectively accommodated heptane rather than the branched homologues. The sorption properties were tunable by slight modification of the calixarene unit, whereby the recognition of E–Z stereochemistry of 2-heptene was achieved.

Hydrophobic micropores created in the crystal lattice of a calix[4]arene–polyoxometalate hybrid (C2-PW) selectively accommodated heptane rather than the branched homologues. The sorption properties were tunable by slight modification of the calixarene unit, whereby the recognition of E–Z stereochemistry of 2-heptene was achieved.

収録刊行物

  • Chemistry letters

    Chemistry letters 36(2), 246-247, 2007-02-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10018522439
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  IR  J-STAGE 
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