Photo-controlled Electrochemical Switch Based on Photochromic Tetraazaporphyrin Containing Ferrocene Units

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  • Lei Sun
    Labs for Advanced Materials and Institute of Fine Chemicals, East China University of Science & Technology
  • Sheng Wang
    Labs for Advanced Materials and Institute of Fine Chemicals, East China University of Science & Technology
  • He Tian
    Labs for Advanced Materials and Institute of Fine Chemicals, East China University of Science & Technology

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<jats:title>Abstract</jats:title> <jats:p>A new photochromic compound of tetraazaporphyrin magnesium(II) appended with eight ferrocene units by ethynyl TPF was synthesized. Its photochromic properties and electrochemical properties were studied. As its redox potential was reversibly changed accompanying the open- and closed-ring photoisomerization of TPF with UV–vis light irradiation, TPF may be used as electrochemical switch controlled by light.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 36 (2), 250-251, 2007-01-13

    Oxford University Press (OUP)

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