Determination of the Absolute Configuration of Quercivorol, (1<i>S</i>,4<i>R</i>)-<i>p</i>-Menth-2-en-1-ol, an Aggregation Pheromone of the Ambrosia Beetle<i>Platypus quercivorus</i>(Coleoptera: Platypodidae)

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  • KASHIWAGI Takehiro
    Department of Biomechanical System, Faculty of Agriculture, Ehime University
  • NAKASHIMA Tadakazu
    Department of Forest Entomology, Forestry and Forest Products Research Institute
  • TEBAYASHI Shin-ich
    Department of Bioresources Science, Faculty of Agriculture, Kochi University
  • KIM Chul-Sa
    Department of Bioresources Science, Faculty of Agriculture, Kochi University

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  • Determination of the Absolute Configuration of Quercivorol, (1S,4R)-p-Menth-2-en-1-ol, an Aggregation Pheromone of the Ambrosia Beetle Platypus quercivorus (Coleoptera: Platypodidae)

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A pair of enantiomers of trans-p-menth-2-en-1-ol, an aggregation pheromone of Platypus quercivorus, was synthesized from (S)- and (R)-limonene. The retention time of the aggregation pheromone from the insect coincided with that of (1S,4R)-p-menth-2-en-1-ol synthesized from (S)-limonene from GC analyses with a chiral column, enabling the absolute configuration of the aggregation pheromone to be determined as (1S,4R).

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