Enantioselective Synthesis of the (1<i>S</i>,5<i>R</i>)-Enantiomer of Litseaverticillols A and B

• MORITA Akira

  Laboratory of Applied Bioorganic Chemistry, Graduate School of Agricultural Science, Tohoku University

• KIYOTA Hiromasa

  Laboratory of Applied Bioorganic Chemistry, Graduate School of Agricultural Science, Tohoku University

• KUWAHARA Shigefumi

  Laboratory of Applied Bioorganic Chemistry, Graduate School of Agricultural Science, Tohoku University

書誌事項

タイトル別名

• Enantioselective Synthesis of the (1S,5R)-Enantiomer of Litseaverticillols A and B

抄録

An enantioselective synthesis of the (1S,5R)-enantiomer of litseaverticillols A and B was accomplished in line with our previously reported synthetic pathway for their (1R,5S)-enantiomer. The use of “EtSCeCl₂” prepared from EtSLi and CeCl₃, instead of previously employed EtSLi itself, for the formation of thiol ester intermediates prevented any undesirable epimerization occurring in the process.

収録刊行物

• Ｂｉｏｓｃｉｅｎｃｅ，　Ｂｉｏｔｅｃｈｎｏｌｏｇｙ，　ａｎｄ　Ｂｉｏｃｈｅｍｉｓｔｒｙ

  Ｂｉｏｓｃｉｅｎｃｅ，　Ｂｉｏｔｅｃｈｎｏｌｏｇｙ，　ａｎｄ　Ｂｉｏｃｈｅｍｉｓｔｒｙ 70 (10), 2564-2566, 2006

  公益社団法人 日本農芸化学会

キーワード

• litseaverticillol
• enantioselective synthesis
• sesquiterpenoid
• anti-HIV

詳細情報

• CRID: 1390282681453741568
• NII論文ID: 10018526248
• NII書誌ID: AA10824164
• DOI: 10.1271/bbb.60253
• ISSN: 13476947
• ISSN: 09168451
• NDL書誌ID: 8524588
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I8524588
• Web Site: http://www.tandfonline.com/doi/pdf/10.1271/bbb.60253
• 本文言語コード: en
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