Enantioselective Epoxidation of Conjugated Z-Olefins with Newly Modified Mn(salen) Complex

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著者

    • EGAMI Hiromichi
    • Department of Chemistry, Faculty of Science, Graduate School, Kyushu University
    • IRIE Ryo
    • Department of Chemistry, Faculty of Science, Graduate School, Kyushu University
    • SAKAI Ken
    • Department of Chemistry, Faculty of Science, Graduate School, Kyushu University
    • KATSUKI Tsutomu
    • Department of Chemistry, Faculty of Science, Graduate School, Kyushu University

抄録

Chiral Mn(salen) complex <B>3</B> bearing a 1-ethyl-1-methylpropyl group at C3, C3′, C5, and C5′ was found to induce higher asymmetry in the epoxidation of conjugated <I>Z</I>-olefins, especially less nucleophilic ones, in the presence of 4-phenylpyridine <I>N</I>-oxide than complex <B>1</B> bearing a <I>t</I>-butyl group at the same carbons. The higher enantioselectivity was considered to be attributable to Me-in-plane conformation of the 1-ethyl-1-methylpropyl group at C3 and C3′.

収録刊行物

  • Chemistry letters

    Chemistry letters 36(1), 46-47, 2007-01-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10018662708
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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