Simple Vanadium(V) Catalyst for Oxidation of Alkane with O_2 under Mild Conditions

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著者

    • KOBAYASHI Hirokazu
    • Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology
    • YAMANAKA Ichiro
    • Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology

抄録

Selective oxidation of cyclohexane and adamantane was performed by simple V(5+) catalyst with 1 atm O<SUB>2</SUB> in acetic acid at 338–393 K. UV–vis and electron spin resonance studies suggested that peroxide species on V(5+) functioned during the oxidation. The oxidation activity was enhanced three times for cyclohexane and 6.5 times for adamantane by addition of a small amount of CF<SUB>3</SUB>SO<SUB>3</SUB>H.

収録刊行物

  • Chemistry letters  

    Chemistry letters 36(1), 114-115, 2007-01-05 

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10018663451
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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