Preparation of Highly Ordered Mesoporous Thiophene-Silica with Spherical Macrostructure

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著者

    • CHO Eun-Bum
    • Polymer Technology Institute, Department of Chemical Engineering, Sungkyunkwan University
    • KIM Dukjoon
    • Polymer Technology Institute, Department of Chemical Engineering, Sungkyunkwan University

抄録

Highly ordered mesoporous thiophene–silica powder was prepared using nonionic PEO–PLGA–PEO triblock copolymer templates and a 2,5-bis(triethoxysilyl)thiophene organosilica precursor under acidic conditions. The mesoporous thiophene–silica materials prepared with the EO<SUB>16</SUB>(L<SUB>29</SUB>G<SUB>7</SUB>)EO<SUB>16</SUB> template were observed to have a well-defined spherical-like external morphology with a diameter of 2–5 μm, and a 2D hexagonal (<I>p</I>6<I>mm</I>) array of mesopores with a lattice constant of 9.55 nm. The thiophene–silica also displayed a large surface area of up to 1410 m<SUP>2</SUP> g<SUP>−1</SUP>.

収録刊行物

  • Chemistry letters  

    Chemistry letters 36(1), 118-119, 2007-01-05 

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10018663476
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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