Zinc(II) and Copper(I)-Ferrocenedicarboxylate Polyhedron and Polygon

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著者

    • KIM Young S.
    • Department of Chemistry Education, Seoul National University
    • KIM Don
    • Department of Chemistry, Pukyong National University
    • CHAE Hee K.
    • Department of Chemistry Education, Seoul National University

抄録

Metal organometallic carboxylates with unusual polyhedral and rectangular shapes have been prepared by the reaction of 1,1′-ferrocenedicarboxylic acid (H<SUB>2</SUB>FDCA) with Zn<SUP>II</SUP> and Cu<SUP>II</SUP> to give [Zn<SUB>6</SUB>O<SUB>2</SUB>(FDCA)<SUB>5</SUB>(H<SUB>2</SUB>O)(DMF)]·(DMF)<SUB>4</SUB> (<B>1</B>), [Zn<SUB>8</SUB>O<SUB>4</SUB>(FDCA)<SUB>6</SUB>(H<SUB>2</SUB>O)<SUB>3</SUB>]·(DMA)<SUB>4</SUB>·(H<SUB>2</SUB>O)<SUB>2</SUB> (<B>2</B>), and [Cu<SUB>4</SUB>(FDCA)<SUB>2</SUB>] (<B>3</B>), respectively (DMF = <I>N</I>,<I>N</I>′-dimethylformamide; DMA = <I>N</I>,<I>N</I>′-dimethylacetoamide). SQUID data of zinc compounds show that iron ions of the ferrocene moieties in the compounds exhibit antiferromagnetic coupling.

収録刊行物

  • Chemistry letters

    Chemistry letters 36(1), 150-151, 2007-01-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10018663734
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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