Cu_2(C_3H_2N_3O_3)_2(C_<10>H_8N_2) : A Hydrogen-bonded Assemblies Supermolecule Containing 1D Channels and Novel Two-coordinated Linear N-Cu-N Configurations
The title compound was successfully synthesized by the simple hydrothermal route. Interestingly, the title compound exhibits a rare two-coordinated linear N–Cu–N configuration around cuprous ions. Furthermore, the title compound is stacked via hydrogen-bond assembly in three dimensions to form the supermolecule with a channel of 3.98(5) × 8.81(1) Å along the <I>b</I> axis, which may be useful in studying the porous coordination materials.
- Chemistry letters
Chemistry letters 36(1), 168-169, 2007-01-05
The Chemical Society of Japan