Carbazole Synthesis by Platinum-catalyzed C–H Functionalizing Reaction Using Water as Reoxidizing Reagent

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  • Mitsuru Yamamoto
    Department of Material Chemistry, Graduate School of Engineering, Kyoto University
  • Seijiro Matsubara
    Department of Material Chemistry, Graduate School of Engineering, Kyoto University

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<jats:title>Abstract</jats:title> <jats:p>Treatment of 1-aminobiphenyl and diphenylamine with catalytic amount of Pt/C in hydrothermal water (250 °C, 4 MPa) affords 9H-carbazole in good yield. In this catalytic cycle, water works as reoxidizing reagent for platinum catalyst.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 36 (1), 172-173, 2006-12-16

    Oxford University Press (OUP)

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