Conversion of (sp^3)C-F Bonds of Alkyl Fluorides to (sp^3)C-Heteroatom (Heteroatom = I, SR, SeR, TeR) Bonds by the Use of Magnesium Reagents Having Heteroatom Substituents

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著者

    • BEGUM Shameem Ara
    • Department of Applied Chemistry, Graduate School of Engineering, Osaka University
    • TERAO Jun
    • Science and Technology Center for Atoms, Molecules and Ions Control, Graduate School of Engineering, Osaka University
    • KAMBE Nobuaki
    • Department of Applied Chemistry, Graduate School of Engineering, Osaka University

抄録

A convenient method for conversion of (sp<SUP>3</SUP>)C–F bonds to (sp<SUP>3</SUP>)C–Z (Z = I, SR, SeR, TeR) bonds has been developed. The reaction proceeds at room temperature using magnesium salts (Z–MgX). S<SUB>N</SUB>2 mechanism for substitiution of <I>primary</I> alkyl fluorides with MgI<SUB>2</SUB> in ether was supported by the inversion of the stereochemistry of the carbon connecting to F.

収録刊行物

  • Chemistry letters  

    Chemistry letters 36(1), 196-197, 2007-01-05 

    The Chemical Society of Japan

参考文献:  18件

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各種コード

  • NII論文ID(NAID)
    10018664141
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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