新重希土類スクッテルダイトリン化物, LnT_4P_<12> (Ln = heavy lanthanide, Y ; T = Fe, Ru, Os) の高圧合成と電気的, 磁気的性質 High-Pressure Synthesis, Electrical and Magnetic Properties of New Skutterudite Phosphides with Heavy Lanthanide (Including Y), LnT_4P_<12> (Ln = Heavy Lanthanide and Y ; T = Fe, Ru and Os)
New filled skutterudite phosphides with heavy lanthanide (including Y), <i>LnT</i><sub>4</sub>P<sub>12</sub> (<i>Ln</i> = heavy lanthanide and Y; <i>T</i> = Fe, Ru and Os) have systematically been prepared at high temperatures and high pressures. The new relationship between lattice constants and atomic numbers of lanthanides was obtained for filled skutterudite phosphides. Electrical and magnetic properties of the skutterudites with heavy lanthanide have been studied at low temperatures. The superconductivity, the paramagnetic behavior, ferromagnetic and antiferromagnetic transitions were found for the new filled skutterudites prepared at high pressure. Thus, these compounds are classified to four groups by their magnetic properties. The physical properties of new filled skutterudite phosphides with heavy lanthanide (including Y) are discussed.
- 高圧力の科学と技術 = The Review of high pressure science and technology
高圧力の科学と技術 = The Review of high pressure science and technology 16(4), 308-312, 2006-11-20
The Japan Society of High Pressure Science and Technology