Reduction of α,β-Unsaturated Ketones with Diphenylsilanes Bearing Several Substituents on Their Phenyl Moiety Catalyzed by Rhodium-Phosphine Complexes
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1,4-Addition product was afforded exclusively by rhodium–phosphine complex-catalyzed hydrosilylation by using 2-cyclohexen-1-one and a dihydrosilane bearing an ether substituent in spite of the fact that dihydrosilanes were believed to give 1,2-addition product selectively.
- Chemistry Letters
Chemistry Letters 36(3), 366-367, 2007-03-05
The Chemical Society of Japan