A New Superlattice of Cyclohexanethiol Self-assembled Monolayers on Au(111) Formed at a Low Solution Temperature

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<jats:title>Abstract</jats:title> <jats:p>High-resolution scanning tunneling microscopy (STM) imaging revealed that cyclohexanethiols (CHTs) on Au(111) form high-density self-assembled monolayers (SAMs) with a (5 × 2√3)R35° superlattice at a low solution temperature of −20 °C. This packing structure is comparable to a (5 × 2√10)R48° superlattice formed at room temperature. From this result, it was found that the two-dimensional structure of CHT SAMs on Au(111) was strongly influenced by the solution temperature, unlike alkanethiol SAMs.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 36 (3), 390-391, 2007-02-03

    Oxford University Press (OUP)

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