Facile Synthesis of Novel Monodisperse Liquid-crystalline Oligomers Based on Michael Adducts from Millipede Cyanoacetates
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- Sadahiro Nakanishi
- Japan Chemical Innovation Institute, Department of Organic and Polymeric Materials, Graduate School of Science and Engineering, Tokyo Institute of Technology
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- Mitsuru Ueda
- Department of Organic and Polymeric Materials, Graduate School of Science and Engineering, Tokyo Institute of Technology
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<jats:title>Abstract</jats:title> <jats:p>Facile synthesis of novel monodisperse liquid-crystalline (LC) oligomers was performed. The functionalization of the end group of 4 (and 6) millipede cyanoacetates with 8 (and 12) mesogenic units by Michael addition reaction produced a monodisperse LC octamer (and dodecamer) in high yields. Differential scanning calorimetry and optical polarizing microscopy revealed LC properties of the synthesized LC monodisperse oligomers. The monodisperse LC oligomers were morphologically stable glass-forming LC materials and exhibited a large variation in nematic phase temperatures in the range of approximately 80 to 300 °C.</jats:p>
収録刊行物
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- Chemistry Letters
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Chemistry Letters 36 (3), 452-453, 2007-02-17
Oxford University Press (OUP)
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詳細情報 詳細情報について
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- CRID
- 1360002219111001856
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- NII論文ID
- 10018830055
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- NII書誌ID
- AA00603318
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- ISSN
- 13480715
- 03667022
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