Photodimerization Mechanism of Bis(3,4,5-trifluorobenzyl) (E,E)-Muconate in a Columnar Assembly in the Crystalline State

この論文にアクセスする

この論文をさがす

著者

    • MORI Yutaka
    • Department of Applied Chemistry, Graduate School of Engineering, Osaka City University
    • MATSUMOTO Akikazu
    • Department of Applied Chemistry, Graduate School of Engineering, Osaka City University

抄録

We have revealed the photoreaction mechanism for the single-crystal-to-single-crystal transformation of bis(3,4,5-trifluorobenzyl) (<I>E</I>,<I>E</I>)-muconate (<B>1</B>) to the corresponding dimer. The [2 + 2] photodimerization randomly occurred in the columnar assembly of monomer molecules in the crystals of <B>1</B>, followed by the formation of a trimer. The photoreaction was directly monitored by an X-ray single crystal structure analysis as well as the product analysis by NMR and MS spectroscopies.

収録刊行物

  • Chemistry letters

    Chemistry letters 36(4), 510-511, 2007-04-05

    The Chemical Society of Japan

参考文献:  22件中 1-22件 を表示

  • <no title>

    RAMAMURTHY V. ed.

    Photochemistry in Organized & Constrained Media, 1991

    被引用文献1件

  • <no title>

    OHASHI Y. ed.

    Reactivity in Molecular Crystals, 1993

    被引用文献1件

  • <no title>

    Organic Solid State Reactions, 2005

    被引用文献1件

  • <no title>

    BRAGA D. ed.

    Making Crystals by Design : Methods, Techniques and Applications, 2007

    被引用文献1件

  • <no title>

    COHEN M. D.

    J. Chem. Soc., 1964

    被引用文献1件

  • <no title>

    SCHMIDT G. M. J.

    Pure Appl. Chem. 27, 647, 1971

    被引用文献1件

  • <no title>

    LAHAV M.

    J. Chem. Soc. B, 1967

    被引用文献1件

  • <no title>

    GREEN B. S.

    J. Chem. Soc. B, 1971

    被引用文献1件

  • <no title>

    MACGILLIVRAY L. R.

    CrystEngComm 4, 37, 2002

    被引用文献1件

  • <no title>

    MACGILLIVRAY L. R.

    CrystEngComm 6, 77, 2004

    被引用文献1件

  • <no title>

    MORI Y.

    Cryst. Growth Des. 7, 377, 2007

    被引用文献1件

  • <no title>

    ODANI T.

    Chem. Commun., 2001

    被引用文献1件

  • <no title>

    MATSUMOTO A.

    J. Polym. Sci., Part A : Polym. Chem. 44, 4952, 2006

    被引用文献1件

  • <no title>

    MATSUMOTO A.

    Polym. J. 35, 93, 2003

    被引用文献1件

  • <no title>

    MATSUMOTO A.

    Top. Curr. Chem. 254, 263, 2005

    被引用文献1件

  • <no title>

    SHELDRICK G. M.

    SHELXS-97, 1997

    被引用文献1件

  • <no title>

    SHELDRICK G. M.

    SHELXL-97, 1997

    被引用文献1件

  • <no title>

    TANAKA K.

    Chem. Rev. 100, 1025, 2000

    被引用文献22件

  • <no title>

    ENKELMANN K.

    J. Am. Chem. Soc. 115, 10390, 1993

    被引用文献2件

  • <no title>

    GAO X.

    Angew. Chem., Int. Ed. 43, 232, 2004

    被引用文献2件

  • <no title>

    MATSUMOTO A.

    J. Am. Chem. Soc. 121, 11122, 1999

    被引用文献3件

  • <no title>

    MATSUMOTO A.

    J. Am. Chem. Soc. 124, 8891, 2002

    被引用文献3件

各種コード

  • NII論文ID(NAID)
    10018880863
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
ページトップへ