Effect of Intramolecular Hydrogen Bonding on Thermolysis of Dioxetane : Unusual Instability of Bicyclic Dioxetanes Bearing a Hydroxynaphthyl Group with Vicinal Substitution Pattern

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Dioxetanes bearing a 1-hydroxynaphthalen-2-yl group <B>4<FONT SIZE="-2">(OH)</FONT></B> or 2-hydroxynaphthalen-1-yl group <B>5<FONT SIZE="-2">(OH)</FONT></B> were found to be significantly unstable thermally in contrast to their methoxynaphthyl-analogs <B>4<FONT SIZE="-2">(OME)</FONT></B> and <B>5<FONT SIZE="-2">(OME)</FONT></B>. The marked instability of <B>4<FONT SIZE="-2">(OH)</FONT></B> and <B>5<FONT SIZE="-2">(OH)</FONT></B> was attributed to the intramolecular hydrogen bonding of a hydroxy group on the naphthalene ring.

収録刊行物

  • Chemistry letters

    Chemistry letters 36(4), 516-517, 2007-04-05

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10018880908
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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