Studies for Direction Dependences of Magnetizations and Magnetic Structure of Chiral Molecule-based Metamagnet, [Mn(hfac)_2]・BNO

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著者

    • NUMATA Youhei
    • Department of Structural Molecular Science, The Graduate School for Advanced Studies
    • INOUE Katsuya
    • Department of Chemistry, Graduate School of Chemistry, Hiroshima University

抄録

We measured angular dependences of single-crystal magnetization for the chiral structural molecule-based metamagnet [Mn(hfac)<SUB>2</SUB>]·BNO<SUP>*</SUP> (<B>1</B>). This crystal shows remarkable crystal direction dependences of spin flip transition in all crystallographic <I>a</I>, <I>b</I>, and <I>c</I> axes and the transitions are observed at different critical magnetic fields (<I>H</I> || <I>a</I>: 640 Oe, <I>H</I> || <I>b</I>: 1000 Oe, and <I>H</I> || <I>c</I>: 1250 Oe at 2 K). These results mean that <B>1</B> has independent antiferromagnetic multi-sublattices. We calculated its possible magnetic structure from magnetic data and constructed magnetic structural model.

収録刊行物

  • Chemistry letters  

    Chemistry letters 36(4), 534-535, 2007-04-05 

    The Chemical Society of Japan

参考文献:  21件

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各種コード

  • NII論文ID(NAID)
    10018881031
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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