遷移金属錯体を用いたポルフィリンの機能化と多量化 : 巨大機能性分子系の構築と課題 Transition Metal-mediated Fuctionalization and Multiplication of Porphyrins toward Giant Functional Systems

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著者

    • 佐竹 彰治 SATAKE Akiharu
    • 奈良先端科学技術大学院大学物質創成科学研究科 Nara Institute of Science and Technology (NAIST), Graduate School of Materials Science

抄録

Functionalization and multiplication of porphyrins by transition metal-mediated reactions (Sonogashira coupling, Negishi coupling, Stille coupling, Mizoroki-Heck alkenylation, Buchwald-Hartwig reaction, Suzuki-Miyaura coupling, cobalt-mediated [2+2+2] cyclization, Grubbs' metathesis reaction, etc.) are reviewed. When the above reactions are applied to porphyrins, diluted conditions (typically 110 mM) are used due to low solubility. As the dilution, relatively large amounts of metal species are used due to decreasing of turn over numbers of the catalysts. Copper reagent is excluded when free base porphyrins are treated without protection. In multiplication of porphyrins by simultaneous multiple metal-mediated couplings, each yield and existence of side-products greatly affect isolation of the target material. In this review, modified conditions and side-reactions are presented to let know the problems to chemists who synthesizes functional porphyrins and develops metal-mediated reactions.

収録刊行物

  • 有機合成化学協会誌 : JOURNAL OF Synthetic Organic Chemistry JAPAN  

    有機合成化学協会誌 : JOURNAL OF Synthetic Organic Chemistry JAPAN 65(4), 298-307, 2007-04-01 

    The Society of Synthetic Organic Chemistry, Japan

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各種コード

  • NII論文ID(NAID)
    10018898514
  • NII書誌ID(NCID)
    AN0024521X
  • 本文言語コード
    JPN
  • 資料種別
    REV
  • ISSN
    00379980
  • NDL 記事登録ID
    8788565
  • NDL 雑誌分類
    ZP11(科学技術--化学・化学工業--有機化学・有機化学工業)
  • NDL 請求記号
    Z17-256
  • データ提供元
    CJP書誌  NDL  J-STAGE 
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