ホウ素クラスター：カルボランの有機化学―合成，構造，立体分子構築への応用―

• 太田 公規

  東北薬科大学薬学部

• 遠藤 泰之

  東北薬科大学薬学部

書誌事項

タイトル別名

• Chemistry of Boron Clusters, Carboranes Synthesis, Structure and Application for Molecular Construction
• ホウソ クラスター カルボラン ノ ユウキ カガク ゴウセイ コウゾウ リッタイ ブンシ コウチク エノ オウヨウ

抄録

The icosahedral boron cluster : dicarba-closo-dodecaboranes (carboranes) are chemical building blocks of high boron content, remarkable chemical stability, spherical geometry and hydrophobic molecular surface. These features of carboranes may allow wide variety of application for molecular construction, medicinal chemistry and materials sciences. However, little attention has been paid to the understanding their nature in view of synthetic organic chemistry. We have aimed to understand their electronic property, reactivity and to apply their spherical geometry for design and synthesis of biologically active molecules and three-dimensional structures. In this review, we describe development of synthetic methods on the carborane cage, evaluation of the characteristic electronic effects and steric effects of carborane, molecular construction based on spatial definition by carborane and evaluation and application of the hydrogen-bonding affinity of carboranes.

収録刊行物

• 有機合成化学協会誌

  有機合成化学協会誌 65 (4), 320-333, 2007

  公益社団法人 有機合成化学協会

キーワード

• carborane
• boron cluster
• synthetic method
• electronic effect
• steric effect
• kinetics
• distorted molecule
• molecular construction
• molecular recognition
• hydrogen bonding

詳細情報

• CRID: 1390001205312629504
• NII論文ID: 10018898672
• NII書誌ID: AN0024521X
• DOI: 10.5059/yukigoseikyokaishi.65.320
• ISSN: 18836526
• ISSN: 00379980
• NDL書誌ID: 8788661
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I8788661
• 本文言語コード: ja
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