Chemiluminescence Detection of Five-membered Heteroaromatic Compounds Using Electrogenerated Tris(2,2'-bipyridine)-ruthenium(III)

この論文にアクセスする

この論文をさがす

著者

抄録

Heteroaromatic compounds, such as 2,5-dimethylthiophene, 2,5-dimethylpyrrole, and 2,5-dimethylfuran, were found to act as reducing agents for the tris(2,2′-bipyridine)ruthenium(III), Ru(bpy)<sub>3</sub><sup>3+</sup>, chemiluminescent reaction. In order to characterize the chemiluminescent reaction of Ru(bpy)<sub>3</sub><sup>3+</sup> with heteroaromatic compounds, we have investigated various mono-, di-, and tri-heteroaromatic compounds. The π-electron density and stability of aromatic rings influence the chemiluminescent efficiency of the reaction. Above all, 2,5-dimethylthiophene produced strong chemiluminescence under acidic conditions. In addition, we confirmed that the rate of the chemiluminescent reaction of Ru(bpy)<sub>3</sub><sup>3+</sup> with 2,5-dimethylthiophene is very fast.

収録刊行物

  • Analytical sciences : the international journal of the Japan Society for Analytical Chemistry  

    Analytical sciences : the international journal of the Japan Society for Analytical Chemistry 23(4), 407-411, 2007-04-10 

    The Japan Society for Analytical Chemistry

参考文献:  25件

参考文献を見るにはログインが必要です。ユーザIDをお持ちでない方は新規登録してください。

各種コード

  • NII論文ID(NAID)
    10018914185
  • NII書誌ID(NCID)
    AA10500785
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    09106340
  • NDL 記事登録ID
    8698365
  • NDL 雑誌分類
    ZP4(科学技術--化学・化学工業--分析化学)
  • NDL 請求記号
    Z54-F482
  • データ提供元
    CJP書誌  NDL  J-STAGE 
ページトップへ