シクロデキストリン含有ポリロタキサン合成の最前線 Recent Progress in Synthesis of Polyrotaxanes Containing Cyclodextrin Wheels
Polyrotaxanes consisting of cyclodextrins (CDs) as wheels and linear polymers such as poly (ethylene glycol) have been widely investigated by a number of research groups since their first discovery by Harada et al. Many attractive concepts and materials based on the unique structure of the polyrotaxanes formed by the end-capping of the pseudopolyrotaxane have been hitherto reported. This review summarizes the recent progress in synthesis of polyrotaxanes containing CD wheels, with emphasis on the synthesis by end-capping methods of pseudopolyrotaxane, along with a related few applications. Supramolecular-crosslinking between a CD host and a guest polymer is also briefly discussed.
日本ゴム協會誌 80(7), 260-265, 2007-07-15
THE SOCIRETY OF RUBBER SCIENCE AND TECHNOLOGYY, JAPAN