Heterometallic Zn2La and ZnLu Complexes Formed by Site-selective Transmetalation of a Dimeric Homotrinuclear Zinc(II) Complex

• Shigehisa Akine

  Department of Chemistry, University of Tsukuba

• Takanori Taniguchi

  Department of Chemistry, University of Tsukuba

• Tatsuya Nabeshima

  Department of Chemistry, University of Tsukuba

抄録

Transmetalation of a dimeric homotrinuclear zinc(II) complex [(3-MeOsalamo)2Zn3] with Lu3+ and La3+ afforded heterometallic dinuclear [(3-MeOsalamo)ZnLu]3+ and trinuclear [(3-MeOsalamo)2Zn2La]3+ complexes, respectively, whose structures were determined by X-ray crystallography. The transmetalation process was investigated by 1H NMR titrations.

収録刊行物

• Chemistry Letters

  Chemistry Letters 35 (6), 604-605, 2006-05-10

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360002219110847104
• NII論文ID: 10019162564
• NII書誌ID: AA00603318
• DOI: 10.1246/cl.2006.604
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/35/6/604/55591813/cl.2006.604.pdf
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