Intramolecular Photocycloaddition of 2-(2-Alkenyloxymethyl)naphthalene-1-carbonitriles Using Glass-Made Microreactors

• Mukae Hirofumi

  Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University

• Maeda Hajime

  Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University

• Nashihara Satoshi

  Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University

• Mizuno Kazuhiko

  Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University

抄録

Intramolecular [2+2] and [2+3] photocycloadditions of 2-(2-alkenyloxymethyl)naphthalene-1-carbonitriles and their photocycloreversion using glass-made microreactors were investigated in comparison with photoreactions under conventional batch conditions. Both the efficiency and regioselectivity were improved by use of glass-made microreactors. These results can be explained by thorough absorption of light and outflow of primary product from the reaction system.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 80 (6), 1157-1161, 2007

  公益社団法人 日本化学会

キーワード

• General Chemistry

詳細情報

• CRID: 1390282679119250944
• NII論文ID: 130004152329
• NII論文ID: 10019586561
• NII書誌ID: AA00580132
• DOI: 10.1246/bcsj.80.1157
• ISSN: 13480634
• ISSN: 00092673
• NDL書誌ID: 8761945
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I8761945
• Web Site: https://academic.oup.com/bcsj/article-pdf/80/6/1157/56268369/bcsj.80.1157.pdf
• 本文言語コード: en
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