A Fluorescent Chemosensor for Copper(II) Based on a Carboxylic Acid-functionalized Tris(2,2′-bipyridine)- ruthenium(II) Complex

• HE Chun-Lian

  College of Chemistry and Chemical Engineering, Central South University Medical College, Hunan Normal University

• REN Feng-Lian

  College of Chemistry and Chemical Engineering, Central South University

• ZHANG Xiao-Bing

  State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry & Chemical Engineering, Hunan University

• DONG Yan-Yan

  State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry & Chemical Engineering, Hunan University

• ZHAO Yan

  State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry & Chemical Engineering, Hunan University

書誌事項

タイトル別名

• A Fluorescent Chemosensor for Copper(II) Based on a Carboxylic Acid-functionalized Tris(2,2'-bipyridine)-ruthenium(II) Complex
• Fluorescent Chemosensor for Copper 2 Based on a Carboxylic Acid functionalized Tris 2 2 bipyridine ruthenium 2 Complex

抄録

In this research, bis(2,2′-bipyridine)(4-methyl-2,2′-bipyridine-4′-carboxylic acid)ruthenium(II)·2PF₆- complex (1), was first used as a fluorescent chemosensor to recognize Cu(II) in EtOH/H₂O (1:1, v/v) solution. The response of the sensor is based on the fluorescence quenching of complex 1 by binding with Cu(II). The analytical performance characteristics of the proposed Cu(II)-sensitive chemosensor were investigated. The sensor can be applied to the quantification of Cu(II) with a linear range covering from 5.0 × 10^-8 to 1.0 × 10^-4 M and a detection limit of 4.2 × 10^-8 M. The experiment results show that the response behavior of 1 to Cu(II) is pH independent in medium condition (pH 4.0 - 8.0), and show excellent selectivity for Cu(II) over other transition metal cations.

収録刊行物

• Analytical Sciences

  Analytical Sciences 22 (12), 1547-1551, 2006

  社団法人 日本分析化学会

キーワード

• Analytical Chemistry

詳細情報

• CRID: 1390282679233730304
• NII論文ID: 130004441220
• NII論文ID: 10020140198
• NII書誌ID: AA10500785
• DOI: 10.2116/analsci.22.1547
• ISSN: 13482246
• ISSN: 09106340
• NDL書誌ID: 8560547
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I8560547
• Web Site: https://link.springer.com/content/pdf/10.2116/analsci.22.1547.pdf
• Web Site: https://link.springer.com/article/10.2116/analsci.22.1547/fulltext.html
• Web Site: http://www.jstage.jst.go.jp/article/analsci/22/12/22_12_1547/_pdf
• 本文言語コード: en
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