Young の式の再考察 Reconsideration of Young's equation

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The Young's equation describes the interfacial equilibrium condition of a liquid droplet on a smooth solid surface. This relation is derived by Thomas Young in 1805. It has been discussed until today after his work. In general, the Young's equation is discussed from the viewpoint of thermodynamics and derived by minimizing the total free energy of the system with intensive parameters in the total free energy kept constant, i.e., the variation of the total free energy is zero. In the derivation, the virtual work variations in the horizontal and vertical directions of the droplet on the smooth solid are considered independently. However, the virtual work variation at the droplet surface depends on the variation of the horizontal and vertical directions. This point has been overlooked in the past studies. In this study, by considering this directional dependency, we derived the modified Young's equation based on the thermodynamics. Finally, we evaluated the modified Young's equation by comparing the analytical solution of the relationship between a contact angle and the contact line radii of the droplet with some experimental data. Moreover, we investigated the line tension itself.

収録刊行物

  • Thermal science and engineering  

    Thermal science and engineering 16(1), 49-60, 2008-01-01 

    The Heat Transfer Society of Japan

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各種コード

  • NII論文ID(NAID)
    10021063909
  • NII書誌ID(NCID)
    AA11358679
  • 本文言語コード
    JPN
  • 資料種別
    ART
  • ISSN
    09189963
  • NDL 記事登録ID
    9395864
  • NDL 雑誌分類
    ZM5(科学技術--科学技術一般--工学・工業)
  • NDL 請求記号
    Z54-J404
  • データ提供元
    CJP書誌  CJP引用  NDL  J-STAGE 
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