Triply interpenetrated structure of {Mn[2](L)2〔Ag[1](CN)2〕2}-{Mn[2](H2O)2〔Ag[1](CN)2〕2}(L=4-CNpy or py-4-aldoxime)

• Takeshi Kawasaki

• Chihiro Kachi-Terajima

• Toshiaki Saito

書誌事項

タイトル別名

• Triply interpenetrated structure of Mn 2 L 2 Ag 1 CN 2 2 Mn 2 H2O 2 Ag 1 CN 2 2 L 4 CNpy or py 4 aldoxime

抄録

Two novel 3D network coordination polymers {Mn(L)2[Ag(CN)2]2}{Mn(H2O)2[Ag(CN)2]2} (L = 4-CNpy (1) or py-4-aldoxime (2)) (4-CNpy = 4-cyanopyridine; py-4-aldoxime = pyridine-4-aldoxime) were synthesized and characterized by using single-crystal X-ray analysis and magnetic measurements. Both complexes have two distinct octahedral manganese atoms, Mn(1) and Mn(2), linked by a [Ag(CN)2]− unit. The pyridine ring of two Ls coordinate at the apical positions of Mn(1). On the other hand, at the apical positions of Mn(2), two H2O are coordinated. The apical axis of Mn(1) is not parallel to the apical axis of Mn(2). Therefore, {Mn[Ag(CN)2]2} networks in 1 and 2 are distorted and form three-dimensional (3D) frameworks. There are large channels in the 3D networks; however, triple interpenetration was found in 1 and 2. From the temperature dependence of magnetic susceptibility, there is very weak antiferromagnetic interaction between the Mn atoms bridged by a [Ag(CN)2]− unit in 1 and 2.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 81 (2), 268-273, 2008

  Tokyo : Chemical Society of Japan

キーワード

• General Chemistry

詳細情報

• CRID: 1523106604703049984
• NII論文ID: 10021073624
• NII書誌ID: AA00580132
• ISSN: 00092673
• ISSN: 13480634
• DOI: 10.1246/bcsj.81.268
• NDL書誌ID: 9373533
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I9373533
• Web Site: https://academic.oup.com/bcsj/article-pdf/81/2/268/56269720/bcsj.81.268.pdf
• 本文言語コード: en
• NDL 雑誌分類:
  • ZP1(科学技術--化学・化学工業)
• データソース種別:
  • NDL
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