Nickel-catalyzed 〔4 + 2 + 2〕-type annulation reaction of cyclobutanones with diynes and enynes

• Shinji Ashida

• Masahiro Murakami

書誌事項

タイトル別名

• Nickel catalyzed 4 2 2 type annulation reaction of cyclobutanones with diynes and enynes

抄録

In the presence of a nickel(0) catalyst, cyclobutanones reacted with diynes to produce bicyclic eight-membered ring ketones. Cyclobutanones acted as a C4 unit in the formal [4+2+2]-type annulation reaction, which proceeded through a ring-expansion of a spirocyclic seven-membered oxanickelacycle to a nine-membered nickelacycle via β-carbon elimination. A similar annulation reaction was also examined with enynes.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 81 (7), 885-893, 2008

  Tokyo : Chemical Society of Japan

キーワード

• General Chemistry

詳細情報

• CRID: 1524232504851773696
• NII論文ID: 10021076964
• NII書誌ID: AA00580132
• ISSN: 00092673
• ISSN: 13480634
• DOI: 10.1246/bcsj.81.885
• NDL書誌ID: 9573911
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I9573911
• Web Site: https://academic.oup.com/bcsj/article-pdf/81/7/885/56270071/bcsj.81.885.pdf
• 本文言語コード: en
• NDL 雑誌分類:
  • ZP1(科学技術--化学・化学工業)
• データソース種別:
  • NDL
  • Crossref
  • CiNii Articles