A S-bridged Co^<III>Au^ICo^<III> Trinuclear Complex with L-Cysteinate Acting as a Flexible Dicarboxylate-type Metalloligand toward Manganese(II)

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Treatment of a S-bridged Co<SUP>III</SUP>Au<SUP>I</SUP>Co<SUP>III</SUP> trinuclear complex [<B>1</B>]<SUP>3+</SUP>, newly prepared from Δ<SUB>L</SUB>-[Co(<small>L</small>-cys-<I>N</I>,<I>S</I>)(en)<SUB>2</SUB>]<SUP>+</SUP> and Au<SUP>I</SUP>, with MnCl<SUB>2</SUB> gave a 1D (Co<SUP>III</SUP><SUB>2</SUB>Mn<SUP>II</SUP>Au<SUP>I</SUP>)<I><SUB>n</SUB></I> polymeric complex, in which two carboxylate groups of [<B>1</B>]<SUP>3+</SUP> bind to two MnCl<SUB>2</SUB> moieties. On the other hand, a discrete Co<SUP>III</SUP><SUB>2</SUB>Mn<SUP>II</SUP>Au<SUP>I</SUP> tetranuclear complex, in which two carboxylate groups of [<B>1</B>]<SUP>3+</SUP> chelate to a Mn(NO<SUB>3</SUB>)<SUB>2</SUB> moiety, was produced by similar treatment of [<B>1</B>]<SUP>3+</SUP> with Mn(NO<SUB>3</SUB>)<SUB>2</SUB>.

収録刊行物

  • Chemistry letters  

    Chemistry letters 37(2), 170-171, 2008-02-05 

    The Chemical Society of Japan

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各種コード

  • NII論文ID(NAID)
    10021077439
  • NII書誌ID(NCID)
    AA00603318
  • 本文言語コード
    ENG
  • 資料種別
    SHO
  • ISSN
    03667022
  • データ提供元
    CJP書誌  J-STAGE 
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