A S-bridged CoIIIAuICoIII Trinuclear Complex with <scp>l</scp>-Cysteinate Acting as a Flexible Dicarboxylate-type Metalloligand toward Manganese(II)

• Takashi Aridomi

  Department of Chemistry, Graduate School of Science, Osaka University

• Keiichi Takamura

  Department of Chemistry, Graduate School of Science, Osaka University

• Asako Igashira-Kamiyama

  Department of Chemistry, Graduate School of Science, Osaka University

• Takumi Konno

  Department of Chemistry, Graduate School of Science, Osaka University

抄録

Treatment of a S-bridged CoIIIAuICoIII trinuclear complex [1]3+, newly prepared from ΔL-[Co(l-cys-N,S)(en)2]+ and AuI, with MnCl2 gave a 1D (CoIII2MnIIAuI)n polymeric complex, in which two carboxylate groups of [1]3+ bind to two MnCl2 moieties. On the other hand, a discrete CoIII2MnIIAuI tetranuclear complex, in which two carboxylate groups of [1]3+ chelate to a Mn(NO3)2 moiety, was produced by similar treatment of [1]3+ with Mn(NO3)2.

収録刊行物

• Chemistry Letters

  Chemistry Letters 37 (2), 170-171, 2008-01-19

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360846644041242752
• NII論文ID: 10021077439
• NII書誌ID: AA00603318
• DOI: 10.1246/cl.2008.170
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/37/2/170/55595843/cl.2008.170.pdf
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